Blar i Department of Chemistry på utgivelsesdato
Viser treff 41-60 av 449
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Accelerated aging of polyvinyl chloride microplastics by UV irradiation: Aging characteristics, filtrate analysis, and adsorption behavior
(Journal article; Peer reviewed, 2023)The extensive use of plastic products by people has led to the prevalence of microplastics (MPs) in aquatic and terrestrial ecosystems. MPs will be able to undergo multiple aging processes and release dissolved organic ... -
Optimized bisubstrate inhibitors for the actin N-terminal acetyltransferase NAA80
(Journal article; Peer reviewed, 2023)Acetylation of protein N-termini is one of the most common protein modifications in the eukaryotic cell and is catalyzed by the N-terminal acetyltransferase family of enzymes. The N-terminal acetyltransferase NAA80 is ... -
Development of an imaging method for in vivo single-cell tracking under high-noise conditions: a proof of principle
(Journal article; Peer reviewed, 2023)This paper reports the development of a positron imaging method for in vivo single-cell tracking under high-noise conditions. Following biological processes spatially and temporally at a single-cell level in a living ... -
Impact assessment culture in the European Union. Time for something new?
(Journal article; Peer reviewed, 2023)Current approaches and cultures for the economic evaluations of environmental and health policies may suffer from excessive reliance on a standard neoclassic economic toolbox that neglects alternative perspectives. This ... -
Gas phase models of hydride transfer from divalent alkaline earth metals to CO2 and CH2O
(Journal article; Peer reviewed, 2023)The reactivity of HMg+, HMgCl, and HMgCl2− in hydride transfer reactions with CO2 and CH2O were studied by means of the reverse reactions—decarboxylation of HCO2MgCln+/0/− and deformylation of CH3OMgCln+/0/− (n = 0–2)—by ... -
Exploring hydrothermal liquefaction (HTL) of digested sewage sludge (DSS) at 5.3 L and 0.025 L bench scale using experimental design
(Journal article; Peer reviewed, 2023)A common perspective within the prospect of a greener future is utilising our waste materials. One waste material of which the world has abundant resources, and where we will keep having resources, is sewage sludge. This ... -
A reliable external calibration method for reaction monitoring with benchtop NMR
(Journal article; Peer reviewed, 2023)Nuclear magnetic resonance (NMR) spectroscopy is a powerful analytical technique with the ability to acquire both quantitative and structurally insightful data for multiple components in a test sample. This makes NMR ... -
Water-Accelerated Decomposition of Olefin Metathesis Catalysts
(Journal article; Peer reviewed, 2023)Water is ubiquitous in olefin metathesis, at levels ranging from contaminant to cosolvent. It is also non-benign. Water-promoted catalyst decomposition competes with metathesis, even for “robust” ruthenium catalysts. ... -
Leaflet Tensions Control the Spatio-Temporal Remodeling of Lipid Bilayers and Nanovesicles
(Journal article; Peer reviewed, 2023)Biological and biomimetic membranes are based on lipid bilayers, which consist of two monolayers or leaflets. To avoid bilayer edges, which form when the hydrophobic core of such a bilayer is exposed to the surrounding ... -
Cytotoxic Natural Products Isolated from Cryptogramma crispa (L.) R. Br.
(Journal article; Peer reviewed, 2023)Parsley fern, Cryptogramma crispa, is a common fern in arctic–alpine regions, and even though this species has been known since ancient times and has been presumed to cause the poisoning of horses, its natural products ... -
Toxicity prediction using target, interactome, and pathway profiles as descriptors
(Journal article; Peer reviewed, 2023)In silico methods are essential to the safety evaluation of chemicals. Computational risk assessment offers several approaches, with data science and knowledge-based methods becoming an increasingly important sub-group. ... -
Probing Catalyst Degradation in Metathesis of Internal Olefins: Expanding Access to Amine-Tagged ROMP Polymers
(Journal article; Peer reviewed, 2023)Ruthenium-promoted ring-opening metathesis polymerization (ROMP) offers potentially powerful routes to amine-functionalized polymers with antimicrobial, adhesive, and self-healing properties. However, amines readily degrade ... -
Co-exposure to UV radiation and crude oil increases acute embryotoxicity and sublethal malformations in the early life stages of Atlantic haddock (Melanogrammus aeglefinus)
(Journal article; Peer reviewed, 2023)Crude oil causes severe abnormalities in developing fish. Photomodification of constituents in crude oil increases its toxicity several fold. We report on the effect of crude oil, in combination with ultraviolet (UV) ... -
Reaction monitoring via benchtop nuclear magnetic resonance spectroscopy: A practical comparison of on-line stopped-flow and continuous-flow sampling methods
(Journal article; Peer reviewed, 2023)The ability for nuclear magnetic resonance (NMR) spectroscopy to provide quantitative, structurally rich information makes this spectroscopic technique an attractive reaction monitoring tool. The practicality of NMR for ... -
A Saddle-Shaped Expanded Porphyrinoid Fitting C60**
(Journal article; Peer reviewed, 2023)We present the synthesis of a new type of an expanded porphyrinoid macrocycle with a saddle-shaped morphology and its complexation of C60 guest molecules. The new macrocycle contains four carbazole and four triazole moieties ... -
Probing the elastic response of lipid bilayers and nanovesicles to leaflet tensions via volume per lipid
(Journal article; Peer reviewed, 2023)Biological and biomimetic membranes are based on lipid bilayers, consisting of two monolayers or leaflets. One important but challenging physical parameter of these membranes is their tension. For a long time, this tension ... -
Mesomeric Acceleration Counters Slow Initiation of Ruthenium-CAAC Catalysts for Olefin Metathesis (CAAC = Cyclic (Alkyl)(Amino) Carbene)
(Journal article; Peer reviewed, 2023)Ruthenium catalysts bearing cyclic (alkyl)(amino)carbene (CAAC) ligands can attain very high productivities in olefin metathesis, owing to their resistance to unimolecular decomposition. Because the propagating methylidene ... -
Enabling Molecular-Level Computational Description of Redox and Proton-Coupled Electron Transfer Reactions of Samarium Diiodide
(Journal article; Peer reviewed, 2023)Samarium diiodide (SmI2, Kagan’s reagent) is a one-electron reductant with applications ranging from organic synthesis to nitrogen fixation. Highly inaccurate relative energies of redox and proton-coupled electron transfer ... -
Adsorption Behavior of Diclofenac on Polystyrene and Poly(butylene adipate-co-terephthalate) Microplastics: Influencing Factors and Adsorption Mechanism
(Journal article; Peer reviewed, 2023)To unveil the intricacies surrounding the interaction between microplastics (MPs) and pollutants, diligent investigation is warranted to mitigate the environmental perils they pose. This exposition delves into the sorption ... -
Comparing the adsorption of methyl orange and malachite green on similar yet distinct polyamide microplastics: Uncovering hydrogen bond interactions
(Journal article; Peer reviewed, 2023)Microplastics (MPs) and dye pollutants are widespread in aquatic environments. Here, the adsorption characteristics of anionic dye methyl orange (MO) and cationic dye malachite green (MG) on polyamide 6 (PA6) and polyamide ...