Di-μ-chlorido-bis­{bis­[N,N-bis­(tri­methyl­sil­yl)amido]­titanium(III)}

Quadri, C. C.; Törnroos, K. W.; Le Roux, E.

dc.contributor.author	Quadri, C. C.
dc.contributor.author	Törnroos, K. W.
dc.contributor.author	Le Roux, E.
dc.date.accessioned	2018-04-24T10:22:47Z
dc.date.available	2018-04-24T10:22:47Z
dc.date.issued	2017
dc.identifier.issn	2414-3146	en_US
dc.identifier.uri	https://hdl.handle.net/1956/17644
dc.description.abstract	The molecular structure of the title compound, [Ti2Cl2(C6H18NSi2)4], shows a binuclear motif of TiIII atoms, formulated as [Ti(μ-Cl)(N(SiMe3)2)2]2, with two μ-Cl atoms bridging two ((Me3Si)2N)2Ti moieties. The coordination environment of both central TiIII atoms is distorted tetrahedral, with a nearly planar four-membered Ti2Cl2 core [Ti—Cl—Ti—Cl = 2.796 (15)°].	en_US
dc.language.iso	eng	eng
dc.publisher	International Union of Crystallography	en_US
dc.relation.ispartof	<a href="http://hdl.handle.net/1956/17643" target="blank">N-Heterocyclic Carbene Complexes of Titanium vel Class of Catalysts for the Copolymerization of Cyclohexene Oxide with CO2</a>	en_US
dc.rights.uri	https://creativecommons.org/licenses/by/4.0/
dc.subject	crystal structure	eng
dc.subject	titanium(III) silylamide complex	eng
dc.subject	chloride-bridged dimer	eng
dc.subject	binuclear complex	eng
dc.title	Di-μ-chlorido-bis{bis[N,N-bis(trimethylsilyl)amido]titanium(III)}	en_US
dc.type	Journal article
dc.type	Peer reviewed
dc.rights.holder	Copyright the authors	en_US
dc.source.articlenumber	x171488
dc.identifier.doi	https://doi.org/10.1107/S2414314617014882
dc.identifier.cristin	1507218
dc.source.journal	IUCrData
dc.source.journal	IUCrData
dc.subject.nsi	VDP::Matematikk og Naturvitenskap: 400::Kjemi: 440	en_US
dc.source.volume	2
dc.source.issue	10