Browsing Bergen Open Research Archive by Author "Wucher, Barbara"

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Selective rearrangement of terminal epoxides into methylketones catalysed by a nucleophilic rhodium-NHC-pincer complex

Jurgens, Eva; Wucher, Barbara; Rominger, Frank; Törnroos, Karl Wilhelm; Kunz, Doris (Peer reviewed; Journal article, 2014-12-22)

An efficient RhI–NHC–pincer catalyst for the highly regioselective Meinwald rearrangement of monoalkylated epoxides into methylketones under mild conditions is presented. The nucleophilic epoxide opening is assisted by ...