Di-μ-chlorido-bis­{bis­[N,N-bis­(tri­methyl­sil­yl)amido]­titanium(III)}

Abstract

The mol­ecular structure of the title compound, [Ti2Cl2(C6H18NSi2)4], shows a binuclear motif of TiIII atoms, formulated as [Ti(μ-Cl)(N(SiMe3)2)2]2, with two μ-Cl atoms bridging two ((Me3Si)2N)2Ti moieties. The coordination environment of both central TiIII atoms is distorted tetra­hedral, with a nearly planar four-membered Ti2Cl2 core [Ti—Cl—Ti—Cl = 2.796 (15)°].