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dc.contributor.authorQuadri, C. C.
dc.contributor.authorTörnroos, K. W.
dc.contributor.authorLe Roux, E.
dc.date.accessioned2018-04-24T10:22:47Z
dc.date.available2018-04-24T10:22:47Z
dc.date.issued2017
dc.identifier.issn2414-3146en_US
dc.identifier.urihttps://hdl.handle.net/1956/17644
dc.description.abstractThe mol­ecular structure of the title compound, [Ti2Cl2(C6H18NSi2)4], shows a binuclear motif of TiIII atoms, formulated as [Ti(μ-Cl)(N(SiMe3)2)2]2, with two μ-Cl atoms bridging two ((Me3Si)2N)2Ti moieties. The coordination environment of both central TiIII atoms is distorted tetra­hedral, with a nearly planar four-membered Ti2Cl2 core [Ti—Cl—Ti—Cl = 2.796 (15)°].en_US
dc.language.isoengeng
dc.publisherInternational Union of Crystallographyen_US
dc.relation.ispartof<a href="http://hdl.handle.net/1956/17643" target="blank">N-Heterocyclic Carbene Complexes of Titanium vel Class of Catalysts for the Copolymerization of Cyclohexene Oxide with CO2</a>en_US
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectcrystal structureeng
dc.subjecttitanium(III) silyl­amide complexeng
dc.subjectchloride-bridged dimereng
dc.subjectbinuclear complexeng
dc.titleDi-μ-chlorido-bis­{bis­[N,N-bis­(tri­methyl­sil­yl)amido]­titanium(III)}en_US
dc.typeDataset
dc.typePeer reviewed
dc.rights.holderCopyright the author.en_US
dc.identifier.doihttps://doi.org/10.1107/s241431461701488
dc.source.journalIUCrData
dc.subject.nsiVDP::Matematikk og Naturvitenskap: 400::Kjemi: 440en_US


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