Browsing Faculty of Science and Technology by Journals "Organometallics"
Now showing items 1-4 of 4
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Phosphine-Based Z‑Selective Ruthenium Olefin Metathesis Catalysts
(Peer reviewed; Journal article, 2016-05-18)Whereas a number of highly Z-selective ruthenium-based olefin metathesis catalysts bearing N-heterocyclic carbene ligands have been reported in recent years, Zselectivity has so far been difficult to achieve for phosphinebased ... -
Pyridine-Stabilized Fast-Initiating Ruthenium Monothiolate Catalysts for Z-Selective Olefin Metathesis
(Peer reviewed; Journal article, 2017)Pyridine as a stabilizing donor ligand drastically improves the performance of ruthenium monothiolate catalysts for olefin metathesis in comparison with previous versions based on a stabilizing benzylidene ether ligand. ... -
Routes to High-Performing Ruthenium–Iodide Catalysts for Olefin Metathesis: Ligand Lability Is Key to Efficient Halide Exchange
(Journal article; Peer reviewed, 2021)Clean, high-yielding routes are described to ruthenium–diiodide catalysts that were recently shown to enable high productivity in olefin metathesis. For the second-generation Grubbs and Hoveyda catalysts (GII: RuCl2(H2IM ... -
Z-Selective Monothiolate Ruthenium Indenylidene Olefin Metathesis Catalysts
(Journal article; Peer reviewed, 2020)Ru-alkylidenes bearing sterically demanding arylthiolate ligands (SAr) constitute one of only two classes of catalyst that are Z-selective in metathesis of 1-alkenes. Of particular interest are complexes bearing pyridine ...