Browsing Department of Chemistry by Author "Maichle-Mössmer, Cäcilia"

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C–H-Bond Activation and Isoprene Polymerization Studies Applying Pentamethylcyclopentadienyl-Supported Rare-Earth-Metal Bis(Tetramethylaluminate) and Dimethyl Complexes

Hollfelder, Christoph O.; Meermann-Zimmermann, Melanie; Spiridopoulos, Georgios; Werner, Daniel; Törnroos, Karl Wilhelm; Maichle-Mössmer, Cäcilia; Anwander, Reiner (Peer reviewed; Journal article, 2019)

As previously shown for lutetium and yttrium, 1,2,3,4,5-pentamethylcyclopentadienyl (C5Me5 = Cp*)-bearing rare-earth metal dimethyl half-sandwich complexes [Cp*LnMe2]3 are now also accessible for holmium, dysprosium, and ...
Nanoscale organolanthanum clusters: Nuclearity-directing role of cyclopentadienyl and halogenido ligands

Buschmann, Dennis A.; Dietrich, H. Martin; Schneider, David; Birkelbach, Verena M.; Stuhl, Christoph; Törnroos, Karl Wilhelm; Maichle-Mössmer, Cäcilia; Anwander, Reiner (Journal article; Peer reviewed, 2020)

Tetramethylaluminato/halogenido(X) ligand exchange reactions in half-sandwich complexes [CpRLa(AlMe4)2] are feasible in non-coordinating solvents and provide access to large coordination clusters of the type [CpRLaX2]x. ...