• Effect of Larger Pore Size on the Sorption Properties of Isoreticular Metal–Organic Frameworks with High Number of Open Metal Sites 

      Dietzel, Pascal D.C.; Georgiev, Peter A.; Frøseth, Morten; Johnsen, Rune E.; Fjellvåg, Helmer; Blom, Richard (Journal article; Peer reviewed, 2020)
      Four isostructural CPO‐54‐M metal‐organic frameworks based on the larger organic linker 1,5‐dihydroxynaphthalene‐2,6‐dicarboxylic acid and divalent cations (M=Mn, Mg, Ni, Co) are shown to be isoreticular to the CPO‐27 ...
    • Nanoscale organolanthanum clusters: Nuclearity-directing role of cyclopentadienyl and halogenido ligands 

      Buschmann, Dennis A.; Dietrich, H. Martin; Schneider, David; Birkelbach, Verena M.; Stuhl, Christoph; Törnroos, Karl Wilhelm; Maichle-Mössmer, Cäcilia; Anwander, Reiner (Journal article; Peer reviewed, 2020)
      Tetramethylaluminato/halogenido(X) ligand exchange reactions in half-sandwich complexes [CpRLa(AlMe4)2] are feasible in non-coordinating solvents and provide access to large coordination clusters of the type [CpRLaX2]x. ...
    • A Saddle-Shaped Expanded Porphyrinoid Fitting C60** 

      Maulbetsch, Theo; Frech, Philipp; Scheele, Marcus; Törnroos, Karl Wilhelm; Kunz, Doris (Journal article; Peer reviewed, 2023)
      We present the synthesis of a new type of an expanded porphyrinoid macrocycle with a saddle-shaped morphology and its complexation of C60 guest molecules. The new macrocycle contains four carbazole and four triazole moieties ...
    • Spin Crossover in a Hexaamineiron(II) Complex: Experimental Confirmation of a Computational Prediction 

      Bernhardt, Paul V.; Bilyj, Jessica K.; Brosius, Victor; Chernyshov, Dmitry; Deeth, Robert J.; Foscato, Marco; Jensen, Vidar Remi; Mertes, Nicole; Riley, Mark J.; Törnroos, Karl Wilhelm (Peer reviewed; Journal article, 2018-01-06)
      Single crystal structural analysis of [Fe^II(tame)_2]Cl_2⋅MeOH (tame=1,1,1‐tris(aminomethyl)ethane) as a function of temperature reveals a smooth crossover between a high temperature high‐spin octahedral d^6 state and a ...