Browsing Department of Chemistry by Journals "Chemistry - A European Journal"
Now showing items 1-4 of 4
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Effect of Larger Pore Size on the Sorption Properties of Isoreticular Metal–Organic Frameworks with High Number of Open Metal Sites
(Journal article; Peer reviewed, 2020)Four isostructural CPO‐54‐M metal‐organic frameworks based on the larger organic linker 1,5‐dihydroxynaphthalene‐2,6‐dicarboxylic acid and divalent cations (M=Mn, Mg, Ni, Co) are shown to be isoreticular to the CPO‐27 ... -
Nanoscale organolanthanum clusters: Nuclearity-directing role of cyclopentadienyl and halogenido ligands
(Journal article; Peer reviewed, 2020)Tetramethylaluminato/halogenido(X) ligand exchange reactions in half-sandwich complexes [CpRLa(AlMe4)2] are feasible in non-coordinating solvents and provide access to large coordination clusters of the type [CpRLaX2]x. ... -
A Saddle-Shaped Expanded Porphyrinoid Fitting C60**
(Journal article; Peer reviewed, 2023)We present the synthesis of a new type of an expanded porphyrinoid macrocycle with a saddle-shaped morphology and its complexation of C60 guest molecules. The new macrocycle contains four carbazole and four triazole moieties ... -
Spin Crossover in a Hexaamineiron(II) Complex: Experimental Confirmation of a Computational Prediction
(Peer reviewed; Journal article, 2018-01-06)Single crystal structural analysis of [Fe^II(tame)_2]Cl_2⋅MeOH (tame=1,1,1‐tris(aminomethyl)ethane) as a function of temperature reveals a smooth crossover between a high temperature high‐spin octahedral d^6 state and a ...