Blar i Department of Chemistry på emneord "VDP::Matematikk og naturvitenskap: 400::Kjemi: 440::Organisk kjemi: 441"
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Selective rearrangement of terminal epoxides into methylketones catalysed by a nucleophilic rhodium-NHC-pincer complex
(Peer reviewed; Journal article, 2014-12-22)An efficient RhI–NHC–pincer catalyst for the highly regioselective Meinwald rearrangement of monoalkylated epoxides into methylketones under mild conditions is presented. The nucleophilic epoxide opening is assisted by ...