dc.contributor.author | Maulbetsch, Theo | |
dc.contributor.author | Frech, Philipp | |
dc.contributor.author | Scheele, Marcus | |
dc.contributor.author | Törnroos, Karl Wilhelm | |
dc.contributor.author | Kunz, Doris | |
dc.date.accessioned | 2023-10-10T12:41:49Z | |
dc.date.available | 2023-10-10T12:41:49Z | |
dc.date.created | 2023-09-28T08:50:06Z | |
dc.date.issued | 2023 | |
dc.identifier.issn | 0947-6539 | |
dc.identifier.uri | https://hdl.handle.net/11250/3095527 | |
dc.description.abstract | We present the synthesis of a new type of an expanded porphyrinoid macrocycle with a saddle-shaped morphology and its complexation of C60 guest molecules. The new macrocycle contains four carbazole and four triazole moieties and can be readily synthesized via a copper-catalyzed click reaction. It shows specific photo-physical properties including fluorescence with a high quantum yield of 60 %. The combination of the saddle-shaped geometry with the expanded π-system allows for host–guest interactions with C60 in a stacked polymer fashion. Evidence for the presence of a host–guest complex is provided both in solution by NMR spectroscopy and in the solid state by X-ray structure analysis. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Wiley | en_US |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internasjonal | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/deed.no | * |
dc.title | A Saddle-Shaped Expanded Porphyrinoid Fitting C60** | en_US |
dc.type | Journal article | en_US |
dc.type | Peer reviewed | en_US |
dc.description.version | publishedVersion | en_US |
dc.rights.holder | Copyright 2023 The Author(s) | en_US |
dc.source.articlenumber | e202302104 | en_US |
cristin.ispublished | true | |
cristin.fulltext | original | |
cristin.qualitycode | 2 | |
dc.identifier.doi | 10.1002/chem.202302104 | |
dc.identifier.cristin | 2179680 | |
dc.source.journal | Chemistry - A European Journal | en_US |
dc.identifier.citation | Chemistry - A European Journal. 2023, e202302104. | en_US |