Incorporation of an intact dimeric Zr12 oxo cluster from a molecular precursor in a new zirconium metal-organic framework

dc.contributor.author	Bezrukov, Andrey
dc.contributor.author	Törnroos, Karl Wilhelm
dc.contributor.author	Le Roux, Erwan
dc.contributor.author	Dietzel, Pascal D.C.
dc.date.accessioned	2024-03-05T08:01:55Z
dc.date.available	2024-03-05T08:01:55Z
dc.date.created	2019-01-07T12:12:52Z
dc.date.issued	2018
dc.identifier.issn	1359-7345
dc.identifier.uri	https://hdl.handle.net/11250/3120997
dc.description.abstract	Two zirconium–organic frameworks were synthesized by exchanging the acetate ligands in [Zr12O8(OH)8(CH3COO)24] with polydentate linkers. Partial substitution of acetate groups by a phosphine based linker yielded a new porous framework with this unique dimeric Zr12 cluster unit as molecular building block. More exhaustive substitution of acetate resulted in cleavage of the Zr12 unit and formation of UiO-67.	en_US
dc.language.iso	eng	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.title	Incorporation of an intact dimeric Zr12 oxo cluster from a molecular precursor in a new zirconium metal-organic framework	en_US
dc.type	Journal article	en_US
dc.type	Peer reviewed	en_US
dc.description.version	acceptedVersion	en_US
dc.rights.holder	Copyright The Royal Society of Chemistry 2018	en_US
cristin.ispublished	true
cristin.fulltext	postprint
cristin.qualitycode	2
dc.identifier.doi	10.1039/c8cc00507a
dc.identifier.cristin	1651426
dc.source.journal	Chemical Communications	en_US
dc.source.pagenumber	2735-2738	en_US
dc.identifier.citation	Chemical Communications. 2018, 54 (22), 2735-2738.	en_US
dc.source.volume	54	en_US
dc.source.issue	22	en_US