Selective rearrangement of terminal epoxides into methylketones catalysed by a nucleophilic rhodium-NHC-pincer complex

Jurgens, Eva; Wucher, Barbara; Rominger, Frank; Törnroos, Karl Wilhelm; Kunz, Doris
Peer reviewed, Journal article
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https://hdl.handle.net/1956/11794
Utgivelsesdato
2014-12-22
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Originalversjon
https://doi.org/10.1039/c4cc07154a
Sammendrag
An efficient RhI–NHC–pincer catalyst for the highly regioselective Meinwald rearrangement of monoalkylated epoxides into methylketones under mild conditions is presented. The nucleophilic epoxide opening is assisted by Lewis acids.
Utgiver
Royal Society of Chemistry
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Copyright 2014 the authors
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Med mindre annet er angitt, så er denne innførselen lisensiert som Attribution CC BY