dc.contributor.author | Occhipinti, Giovanni | |
dc.contributor.author | Törnroos, Karl Wilhelm | |
dc.contributor.author | Jensen, Vidar Remi | |
dc.date.accessioned | 2018-08-07T12:02:31Z | |
dc.date.available | 2018-08-07T12:02:31Z | |
dc.date.issued | 2017 | |
dc.Published | Occhipinti G, Törnroos KW, Jensen VR. Pyridine-Stabilized Fast-Initiating Ruthenium Monothiolate Catalysts for Z-Selective Olefin Metathesis. Organometallics. 2017;36(17):3284-3292 | eng |
dc.identifier.issn | 1520-6041 | en_US |
dc.identifier.issn | 0276-7333 | en_US |
dc.identifier.uri | https://hdl.handle.net/1956/18015 | |
dc.description.abstract | Pyridine as a stabilizing donor ligand drastically improves the performance of ruthenium monothiolate catalysts for olefin metathesis in comparison with previous versions based on a stabilizing benzylidene ether ligand. The new pyridine-stabilized ruthenium alkylidenes undergo fast initiation and reach appreciable yields combined with moderate to high Z selectivity in self-metathesis of terminal olefins after only a few minutes at room temperature. Moreover, they can be used with a variety of substrates, including acids, and promote self-metathesis of ω-alkenoic acids. The pyridine-stabilized ruthenium monothiolate catalysts are also efficient at the high substrate dilutions of macrocylic ring-closing metathesis and resist temperatures above 100 °C during catalysis. | en_US |
dc.language.iso | eng | eng |
dc.publisher | American Chemical Society | en_US |
dc.rights | Attribution CC BY | eng |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0 | eng |
dc.title | Pyridine-Stabilized Fast-Initiating Ruthenium Monothiolate Catalysts for Z-Selective Olefin Metathesis | en_US |
dc.type | Peer reviewed | |
dc.type | Journal article | |
dc.date.updated | 2018-03-06T12:54:30Z | |
dc.description.version | publishedVersion | en_US |
dc.rights.holder | Copyright 2017 American Chemical Society | en_US |
dc.identifier.doi | https://doi.org/10.1021/acs.organomet.7b00441 | |
dc.identifier.cristin | 1544250 | |
dc.source.journal | Organometallics | |
dc.relation.project | Norges forskningsråd: 208335 | |
dc.relation.project | Norges forskningsråd: 239288 | |
dc.relation.project | Norges forskningsråd: 226244 | |