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dc.contributor.authorHedwig, Gavin R.
dc.contributor.authorJameson, Geoffrey B.
dc.contributor.authorHøiland, Harald
dc.date.accessioned2021-04-20T11:23:02Z
dc.date.available2021-04-20T11:23:02Z
dc.date.created2020-03-02T13:47:18Z
dc.date.issued2019
dc.PublishedJournal of Solution Chemistry. 2019, 48 (2), 180-199.
dc.identifier.issn0095-9782
dc.identifier.urihttps://hdl.handle.net/11250/2738640
dc.description.abstractSpeeds of sound have been measured for aqueous solutions of the nucleosides adenosine, cytidine, and uridine at the temperatures T = (288.15 and 313.15) K and at the pressures p = (10, 20, 40, 60, 80, and 100) MPa. Using the methods described in our previous work, the partial molar volumes at infinite dilution, Vo2, the partial molar isentropic compressions at infinite dilution, KoS,2, and the partial molar isothermal compressions at infinite dilution, KoT,2{KoT,2=−(∂Vo2/∂p)T)}, for the nucleosides were derived from the speed of sound data at elevated pressures. The thermodynamic properties Vo2 and KoT,2 were combined with those determined previously for T = 298.15 K to create 3D surfaces that display the pressure and temperature dependences of these properties. The purine nucleoside adenosine displays distinctly different trends in these properties from those of the pyrimidine nucleosides cytidine and uridine. A semi-empirical model was used to rationalize the KoT,2 results in terms of likely changes in hydration as a function of temperature and pressure.en_US
dc.language.isoengen_US
dc.publisherSpringeren_US
dc.titleVolumetric properties of the nucleosides adenosine, cytidine, and uridine in aqueous solution at T = (288.15 and 313.15) K and p = (10 to 100) MPaen_US
dc.typeJournal articleen_US
dc.typePeer revieweden_US
dc.description.versionacceptedVersionen_US
dc.rights.holderCopyright Springer Science+Business Media, LLC, part of Springer Nature 2019en_US
cristin.ispublishedtrue
cristin.fulltextpostprint
cristin.qualitycode1
dc.identifier.doi10.1007/s10953-019-00856-4
dc.identifier.cristin1798943
dc.source.journalJournal of Solution Chemistryen_US
dc.source.4048
dc.source.142
dc.source.pagenumber180-199en_US
dc.identifier.citationJournal of Solution Chemistry. 2019, 48, 180–199en_US
dc.source.volume48en_US


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